Early solar system aqueous activity: K isotope evidence from Allende

The alkali element K is moderately volatile and fluid mobile; thus, it can be influenced by both primary processes (evaporation and recondensation) in the solar nebula and secondary processes (thermal and aqueous alteration) in the parent body. Since these primary and secondary processes would induce different isotopic fractionations, K isotopes could become a potential tracer to distinguish them. Using recently developed methods with improved precision (0.05‰, 95% confidence interval), we systematically measured the K isotopic compositions and major/trace elemental compositions of chondritic components (18 chondrules, 3 CAIs, 2 matrices, and 5 bulks) in the carbonaceous chondrite fall Allende. Among all the components analyzed in this study, CAIs, which formed initially under high‐temperature conditions in the solar nebula and were dominated by nominally K‐free refractory minerals, have the highest K₂O content (average 0.53 wt%) and have K isotope compositions most enriched in heavy isotopes (δ⁴¹K: ?0.30 to ?0.25‰). Such an observation is consistent with previous petrologic studies that show CAIs in Allende have undergone alkali enrichment during metasomatism. In contrast, chondrules contain lower K₂O content (0.003–0.17 wt%) and generally lighter K isotope compositions (δ⁴¹K: ?0.87‰ to ?0.24‰). The matrix and bulks are nearly identical in K₂O content and K isotope compositions (0.02–0.05 wt%; δ⁴¹K: ?0.62 to ? 0.46‰), which are, as expected, right in the middle of CAIs and chondrules. This strongly indicates that most of the chondritic components of Allende suffered aqueous alteration and their K isotopic compositions are the ramification of Allende parent‐body processing instead of primary nebular signatures. Nevertheless, we propose the small K isotope fractionations observed (< 1‰) among Allende components are likely similar to the overall range of K isotopic fractionation that occurred in nebular environment. Furthermore, the K isotope compositions seen in the components of Allende in this study are consistent with MC‐ICP‐MS analyses of the components in ordinary chondrites, which also show an absence of large (10‰) isotope fractionations. This is not expected as evaporation experiments in nebular conditions suggest there should be large K isotopic fractionations. Nevertheless, possible nebular processes such as chondrules back exchanging with ambient gas when they formed could explain this lack of large K isotopic variation.     

Using hysteretic behaviour and hydrograph classification to identify hydrological function across the “hillslope–depression–stream” continuum in a karst catchment

In cockpit karst landscapes, fluxes from upland areas contribute large volumes of water to low-lying depressions and stream flow. Hydrograph hysteresis and similarity between monitoring sites is important for understanding the space–time variability of hydrologic responses across the “hillslope–depression–stream” continuum. In this study, the hysteretic feature of hydrographs was assessed by characterizing the loop-like relationships between responses at upstream sites relative to subsurface discharge at the outlet of a small karst catchment. A classification of hydrograph responses based on the multi-scale smoothing Kernel -derived distance classifies the hydrograph responses on the basis of similarities between hillslope and depression sites, and those at the catchment outlet. Results demonstrate that the temporal and spatial variability of hydrograph hysteresis and similarity between hillslope flow and outlet stream flow can be explained by the local heterogeneity of depression aquifer. Large depression storage deficits emerging in the highly heterogeneous aquifer produce strong hysteresis and multiple relationships of upstream hydrographs relative to the outlet subsurface discharge. In contrast, when depression storage deficits are filled during consecutive rainfall events, depression hydrographs at the high permeability sites are almost synchronous or exhibit a monotonous function with the hydrographs at the outlet. This reduced hydrograph hysteresis enhances preferential flow paths in fractured rocks and conduits that can accelerate the hillslope flow to the outlet. Therefore, classification of hydrograph similarities between any upstream sites and the catchment outlet can help to identify the dominant hydrological functions in the heterogeneous karst catchment.     

Investigation of the elevation of saltwater wedge due to subsurface dams

Subsurface dams are rather effective and used for the prevention of saltwater intrusion in coastal regions around the world. We carried out the laboratory experiments to investigate the elevation of saltwater wedge after the construction of subsurface dams. The elevation of saltwater wedge refers to the upward movement of the downstream saltwater wedge because the subsurface dams obstruct the regional groundwater flow and reduce the freshwater discharge. Consequently, the saltwater wedge cannot further extend in the longitudinal direction but rises in the vertical profile resulting in significant downstream aquifer salinization. In order to quantitatively address this issue, field-scale numerical simulations were conducted to explore the influence of various dam heights, distances, and hydraulic gradients on the elevation of saltwater wedge. Our investigation shows that the upward movement of the saltwater wedge and its areal extension in the vertical domain of the downstream aquifer become more severe with a higher dam and performed a great dependence on the freshwater discharge. Furthermore, the increase of the hydraulic gradient and the dam distance from the sea boundary leads to a more pronounced wedge elevation. This phenomenon comes from the variation of the freshwater discharge due to the modification of dam height, location, and hydraulic gradient. Large freshwater discharge can generate greater repulsive force to restrain the elevation of saltwater wedge. These conclusions provide theoretical references for the behaviour of the freshwater–seawater interface after the construction of subsurface dams and help optimize the design strategy to better utilize the coastal groundwater resources.     

城市“腾笼换鸟”产业转型升级的困境与出路——基于北京市的调查研究

剖析北京“腾笼换鸟”产业转型升级的现状,在针对“新鸟”进笼“老鸟”去哪问题,“老笼”空间结构合理优化问题,“老鸟”涅槃“新鸟”培育问题,“老鸟”和“新笼”承接问题的分析基础上,提出应完善京津冀产业链协作,“腾笼换鸟”拓展区域联动发展空间;东西城合并成首都特区,“腾笼换鸟”保护北京历史文化名城;切实发挥政府的职能作用,“腾笼换鸟”提升企业内在动力机制;规划建设“微中心”小城镇,“腾笼换鸟”促进北京人口有效疏解的建议。     

城市内涝灾害受灾人口评估方法与实证研究：以哈尔滨市道里区为例

城市内涝灾害频发,对居民生命安全造成严重威胁,为提高城市内涝灾害受灾人口评估精度,提出一种更为精确的受灾人口评估方法。以哈尔滨市道里区为研究区,以城市内涝灾害受灾人口为研究对象,运用一、二维非恒定流为主控方程,构建城市内涝数值模拟模型,并结合受灾人口分布特点,综合构建基于土地利用的人口随时间变化的计算模型。实现在模拟内涝灾害影响范围基础上,利用受灾人口计算模型提取白天与夜晚受灾人口分布情况。结果表明：研究区在百年一遇降雨情景下,有25条街道会发生不同程度积水,积水深度范围值为0.10~1.42 m;此级别内涝灾害在白天11条街道受灾人口数量最大值达到3 500人,夜晚10条街道受灾人口数量最大值为720人。     

乡土地理实践活动案例分析与应用——以“明光市女山古火山地质公园考察”为例

地理实践是地理科学的重要研究方法,也是中学地理学科的主要学习方式之一。中学地理实践活动应结合乡土地理资源,充分挖掘当地可供考察的自然、人文素材,形成丰富的乡土地理实践案例。本文以“女山古火山地质公园实践活动为案例”,探究乡土资源在地理实践活动中的应用。     

青海湖沙柳河流域浅层地下水不同时期补给特征

地下水稳定同位素组成的时空变化特征可以反映不同时期、不同区域地下水补给来源的差异。通过青海湖沙柳河流域浅层地下水氢氧稳定同位素组成的时空变化特征以及地下水、河水与降雨之间的补给关系的分析，结果显示：季风时期，地下水主要受降雨入渗和河流侧向补给为主，在补给过程中蒸发作用是影响地下水稳定同位素值的主要因素；非季风期，冰雪融水对低值区的地下水影响显著，同时降水的快速入渗则是该时期高值区地下水的主要补给方式之一。地下水同位素高值区，地下水与河水间补给作用较弱，补给时间超过5个月；地下水同位素低值区，地下水与河水补给关系较为密切，补给时间在1~4个月间。本文所得结论可初步反映干旱半干旱内陆流域地下水稳定同位素特征以及补给方式的基本规律，在一定程度上可为流域地下水及其他水体间的转换研究提供科学依据，并为地下水资源管理和水环境治理提供一定理论指导。     

新疆乡村聚落特征及其区域融合发展探析

把握兵地聚落差异，以期为新疆兵地融合发展提供理论依据。基于土地利用数据，运用探 索式空间统计模型定量分析天山北坡兵地乡村聚落空间格局与经济发展差异，并基于其差异对其 融合发展提出相应对策。结果表明：（1）天山北坡兵团与地方乡村聚落在空间、规模、区位以及形 态分布特征上均呈现出明显的空间差异，乡村聚落空间整体上呈集聚分布模式，地方聚落集聚态 势较明显；聚落规模呈低值集聚的分布特征，兵团聚落大多为大规模聚落斑块，地方聚落则相反； 乡村聚落的分布具有明显的高程、坡度、道路、河流、城镇指向性，而兵团聚落分布于区位条件较差 地区；在乡村聚落的外部形态复杂度上，地方聚落大于兵团聚落；（2）经济发展方面，天山北坡整体 经济发展较为良好，兵团人均地区生产总值较高，以农业作为主要产业，地方经济结构较为多样， 除农业外，牧业也是其主要产业；（3）基于兵地聚落间差异，提出相应的融合对策，在空间格局上， 根据实际情况适当进行兵地聚落的迁移合并；在经济发展方面，有效利用优势互补原则，推进兵地 间产业融和。     

贵州夜郎湖表层水体地球化学昼夜变化及其影响因素

为探究岩溶水库水文地球化学行为过程,对贵州普定夜郎湖表层水体进行了为期3 d的高分辨率昼夜监测。结果表明：1）多变的天气和水文条件叠加导致水体离子指标昼夜变化不显著,规律性较差。而水温、DO、pH值、SpC、SIc、pCO₂等常规理化指标受水温变化和生物作用表现出明显的昼夜波动。2）利用亨利常数和主成分分析,得到温度变化、生物作用、人类活动、水库的蓄水与放水对夜郎湖水库水文地球化学特征变化的贡献率分别为21.66%、17.28%、14.08%和10.22%,说明作用于水库水文地球化学行为的因子具有多元性。3）δ ¹⁸O表现出与DO一致的波动趋势,即白天上升,晚上下降,反映在短时间尺度上,氢氧稳定同位素变化受控于生物过程（主要是呼吸作用过程）;而对比水库水体和大气降水的d-excess（d值）发现,水库水体的d值（8.21‰）显著偏低于当地大气降水的d值（9.64‰）,说明在长时间尺度上,主要受蒸发效应引起的不平衡分馏影响。     

三元插层材料的合成及其在聚丙烯老化中的应用

以FeCl3?6H2O、NiCl2?6H2O、MgCl2?6H2O为原料，以NaOH为沉淀剂采用水热法合成了镁镍铁水滑石 (MgNiFe-LDH)，通过X射线衍射 (XRD)、傅里叶变换红外光谱 (FTIR) 和扫描电镜 (SEM) 分析了MgNiFe-LDH结构及形貌，探讨了不同陈化时间和水热温度对MgNiFe-LDH合成的影响。将制得的MgNiFe-LDH添加至聚丙烯 (PP) 中，制备MgNiFe-LDH/PP复合材料，通过对材料的加速老化测其力学性能，研究了添加MgNiFe-LDH前后材料力学性能的差异。研究结果表明，当Mg2+:Ni2+:Fe3+=2:1:1，反应温度为140℃、陈化时间为24 h时，合成的MgNiFe-LDH为片状，形貌较为规整，颗粒粒径约为2μm；经加速老化后，填充MgNiFe-LDH 复合材料的抗老化性能优于纯PP，当MgNiFe-LDH的填充量为6 wt% 复合材料拉伸强度不变，可明显提高PP的抗老化性能。